However I think I might now know. I had to clean out a bottle full of the slimy stuff this evening, and some of the blackish greenish mess had picked up the blue colour from the additive that had been put in after the horrible gunk had formed. So some of it looked decidely like the additive had been the cause of the gunk.
I remain convinced the gunk had been caused when plain water was used, and only appeared to be due to the additive because that came after the gunk was formed.
Apologies if this makes no sense to anyone, I've been sniffing washer fluid fumes.......